AbstractThe viability of recycling post-industrial packaging waste, compounded from multilayer laminated PET-PE films, for production of polymer blends with good physico-mechanical performance is analyzed. Initially, several PET-PE model-blends were prepared from fresh polymers and were compounded with different formulations, based on design of experiments (DOE). Polymer compatibilizers based on maleic anhydride (PE-g-MA) and glycidyl methacrylate (E-GMA) have been used to promote the compatibilization reaction. The physico-mechanical properties of the model-blends were evaluated by response surface methodology (RSM). Finally, the post-industrial waste was compounded with the same concentration of compatibilizers in the previous set of model-blends. The DOE methodology showed to be a useful tool for assessing the recycling, since it helped to produce recycled materials with acceptable physico-mechanical properties. Between both compatibilizers studied, PE-g-MA showed to be the best additive for compatibilization due to the presence of a polyamide component in the waste, which undergoes a kinetically favorable compatibilization reaction.